Journal
TETRAHEDRON
Volume 64, Issue 8, Pages 1635-1640Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.12.020
Keywords
amino alcohols; asymmetric catalysis; boron; pinene
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Both cis- and trans-1,2-amino alcohols 5 and their N-alkylated derivatives 6 were prepared from (-)-alpha-pinene 7 as chirality source and utilized in asymmetric borane reduction of arylketones 12 employing a one-pot multi-substrate screening. The oxazaborolidine catalysts were generated in situ from amino alcohols 5 and 6 and trimethyl borate. (C) 2008 Elsevier Ltd. All rights reserved.
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