Metal organic frameworks/macroporous carbon composites with enhanced stability properties and good electrocatalytic ability for ascorbic acid and hemoglobin

The thermal, water and electrochemical stability of Cu-based metal organic frameworks (Cu-MOFs) confined in macroporous carbon (MPC) hybrids has been investigated. Thermogravimetric analyses, X-Ray diffraction, scanning electron microscopy, and cyclic voltammetry were employed to confirm the stability of pure Cu-MOFs, MPC, and Cu-MOFs-MPC. As compared to pure Cu-MOFs, the porous composite materials of MPC and Cu-MOFs interact and seem to form new materials having homogenous structure and chemistry, which show structural stability in aqueous media and electrochemical stability in phosphate buffer solution (PBS pH 7.4). The detection of ascorbic acid and hemoglobin is performed as an electrochemical probe, indicating Cu-MOFs-MPC holds great promise for the design of electrochemical sensors. (C) 2014 Elsevier B.V. All rights reserved.