Copper nanoparticles: A new colorimetric probe for quick, naked-eye detection of sulfide ions in water samples

This study introduces a new method for the visual and spectrophotometric detection of chemical species using copper nanoparticles (Cu NPs). A simple method for the synthesis of Cu NPs for rapid calorimetric visual detection of sulfide ions (S2-) in water samples is described. The Cu NPs sensor detects sensitive and selective color change in the presence of micromolar levels of S2- that can be observed with the naked eye and monitored using a UV-vis spectrophotometer. The color change quantitatively correlates with the concentration of S2- from 12.5 x 10(-6) M to 50.0 x 10(-6) M. Samples of tap water and river water were spiked and analyzed using the proposed system. The results showed that the sensor exhibited excellent detection for S2- in the water samples. A main advantage of the new method is that it provides good selectivity for detecting S2- without the need for complex readout equipment. The proposed method has a high potential for rapid environmental monitoring of sulfide ions. (C) 2014 Elsevier B.V. All rights reserved.