4.7 Article

Versatile microanalytical system with porous polypropylene capillary membrane for calibration gas generation and trace gaseous pollutants sampling applied to the analysis of formaldehyde, formic acid, acetic acid and ammonia in outdoor air

Journal

TALANTA
Volume 83, Issue 1, Pages 84-92

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2010.08.045

Keywords

Microvolume membrane diffusion scrubber; Calibration gas generator; Capillary electrophoresis; Contactless conductivity detection; Spectrophotometry; Carboxylic acids; Ammonia; Microporous capillary hollow fiber; Analysis of air pollution

Funding

  1. Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)
  2. Conselho Nacional para o Desenvolvimento Cientifico e Tecnologico (CNPq)

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The analytical determination of atmospheric pollutants still presents challenges due to the low-level concentrations (frequently in the mu g m(-3) range) and their variations with sampling site and time In this work a capillary membrane diffusion scrubber (CMDS) was scaled down to match with capillary electrophoresis (CE) a quick separation technique that requires nothing more than some nanoliters of sample and when combined with capacitively coupled contactless conductometric detection ((CD)-D-4) is particularly favorable for ionic species that do not absorb in the UV-vis region like the target analytes formaldehyde formic acid acetic acid and ammonium The CMDS was coaxially assembled inside a PTFE tube and fed with acceptor phase (deionized water for species with a high Henry s constant such as formaldehyde and carboxylic acids or acidic solution for ammonia sampling with equilibrium displacement to the non-volatile ammonium ion) at a low flow rate (8 3 nLs(-1)) while the sample was aspirated through the annular gap of the concentric tubes at 25 mLs(-1) A second unit in all similar to the CMDS was operated as a capillary membrane diffusion emitter (CMDE) generating a gas flow with know concentrations of ammonia for the evaluation of the CMDS The fluids of the system were driven with inexpensive aquarium air pumps and the collected samples were stored in vials cooled by a Peltier element Complete protocols were developed for the analysis in air of NH3 CH3COOH HCOOH and with a derivatization setup CH2O by associating the CMDS collection with the determination by CE-(CD)-D-4 The ammonia concentrations obtained by electrophoresis were checked against the reference spectrophotometric method based on Berthelot s reaction Sensitivity enhancements of this reference method were achieved by using a modified Berthelot reaction solenoid micro-pumps for liquid propulsion and a long optical path cell based on a liquid core waveguide (LCW) All techniques and methods of this work are in line with the green analytical chemistry trends (C) 2010 Elsevier B V All rights reserved

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