Triethanolamine-capped CdSe quantum dots as fluorescent sensors for reciprocal recognition of mercury (II) and iodide in aqueous solution

Water-soluble luminescent CdSe quantum dots surface-modified with triethanolamine (TEA-CdSe-QDs) were prepared with high stability. The fluorescence of the TEA-CdSe-QDs was greatly quenched only when Hg2+ and I- coexisted in the solution, whereas addition of either Hg2+ or I- individually has no noticeable effect on the fluorescence emission. Such a unique quenching effect could be used for reciprocal recognition of mercury (II) ions and/or iodide anions in aqueous solution with rather high selectivity and sensitivity. The detection limits of Hg2+ or I- ion were 1.9 x 10(-7) mol L-1 or 2.8 x 10(-7) mol L-1, respectively. The adequate experiments showed that iodine (I) anions could bridge between TEA-CdSe-QDs and Hg2+ to form a stable complex (QDs-I--Hg2+) and the following effective electron transfer from the QDs to the Hg2+ could be responsible for the fluorescence quenching of QDs. (c) 2008 Elsevier B.V. All rights reserved.