4.5 Article

Observation of the solid-state formation of a TTF-CA complex by terahertz spectroscopy

Journal

SYNTHETIC METALS
Volume 158, Issue 7, Pages 278-282

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.synthmet.2008.01.014

Keywords

TTF-CA; solvent-free reaction; terahertz; far infrared spectrometry; molecular crystal; charge-transfer complex

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The solid-state synthesis of a tetrathiafulvalene-chloranil (TTF-CA) complex was demonstrated, and progress in the formation of the complex was monitored using a GaP Raman terahertz (THz) spectrometer. Clear transitions in the THz absorption spectra indicated that the mixture of TTF and CA became the black phase TTF-CA complex. The results of X-ray diffraction, Raman scattering, and FTIR spectra are presented as supporting evidence. supporting evidence.(c) 2008 Elsevier B.V. All rights reserved.

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