Journal
SYNTHETIC COMMUNICATIONS
Volume 43, Issue 19, Pages 2622-2626Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2012.725795
Keywords
1; 3-Dienylphosphonates; diethyl phosphite; Pd-catalyzed; propargylic substitution
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Funding
- Scientific Research Project of the Department of Education of Liaoning Province of China [L2010048]
- Planned Science and Technology Project of Dalian [2011J21DW010]
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An efficient route to the synthesis of 1,3-dienylphosphonates (1) has been developed for the first time by the substitution of propargylic esters (2) to the diethyl phosphite (3) nucleophile in the presence of Pd-2(dba)(3)center dot CHCl3 (2mol %) and 2,2-bis(diphenylphosphino)-1,1-binaphthyl (4mol%). Both the alkyl and aryl 1,3-dienylphosphonates can be prepared from this transformation. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
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