4.3 Article

EFFICIENT ONE-STEP SYNTHESIS OF C3-SYMMETRICAL BENZENOID COMPOUNDS MEDIATED BY SOCl2/EtOH

Journal

SYNTHETIC COMMUNICATIONS
Volume 42, Issue 24, Pages 3569-3578

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2011.585731

Keywords

Aryl methyl ketone; carbazole; C-3-symmetrical molecules; cyclotrimerization; thionyl chloride

Funding

  1. Higher School Science and Technology Development Project of Shanxi Province Education Department [2010124]
  2. Higher School Students Science and Technology Innovation Project of Shanxi Province [[2011]11, 2011332]
  3. Project of Xinzhou Teachers University [[2011]52]

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An efficient one-step synthesis of branched functionalized benzenoid compounds from aryl methyl ketones mediated by SOCl2/EtOH is described; some novel C-3-symmetrical molecules were prepared with satisfactory yields. The method enjoys short reaction time and simple operation, and avoids use of organometallic reagents.

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