Journal
SYNTHETIC COMMUNICATIONS
Volume 42, Issue 4, Pages 608-619Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2010.528129
Keywords
Aerobic oxidation; catalytic oxidation; hydroperoxidation; hydroperoxypyrrolidinediones; manganese(III) acetate; 2,4-pyrrolidinediones
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Funding
- Japan Society for the Promotion of Science [19550046]
- Grants-in-Aid for Scientific Research [22550041] Funding Source: KAKEN
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3-Alkyl-substituted 2,4-pyrrolidinediones were directly oxidized under very mild manganese(III)-catalyzed aerobic oxidation conditions to give the corresponding 3-hydroperoxy-2,4-pyrrolidinediones in quantitative yields. The scope and limitations for the synthesis of the hydroperoxyprrolidinediones are described.
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