4.3 Article

SYNTHETIC APPROACH TO 4a-METHYLTETRAHYDROFLUORENE-TYPE DITERPENOIDS VIA AN AROMATIC OXIDATION OF PHENOL DERIVATIVES

Journal

SYNTHETIC COMMUNICATIONS
Volume 41, Issue 22, Pages 3385-3402

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2010.518274

Keywords

Aromatic oxidation; dichroanone; diterpenoid; hypervalent iodine reagent; 4a-methyltetrahydrofluorene skeleton

Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology of Japan

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An intramolecular aromatic oxidation of a phenolic compound with a hypervalent iodine reagent afforded the coupling product, in which the coupling took place at the para-position of the methoxy goup of the starting material instead of the desired para-position of the isopropenyl group, unfortunately.

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