4.3 Article

TRANSFER HYDROGENATIONS OF NITROBENZENE USING GLYCEROL AS SOLVENT AND HYDROGEN DONOR

Journal

SYNTHETIC COMMUNICATIONS
Volume 41, Issue 22, Pages 3409-3416

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2010.518276

Keywords

Aniline; catalysis; glycerol; green solvent; transfer hydrogenation

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Aniline has been successfully produced by catalytic transfer hydrogenation of nitrobenzene in glycerol, which was employed as both a green solvent and a hydrogen donor. As a solvent, glycerol also facilitated easy separation of the product and recycling of the catalyst.

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