Journal
SYNTHETIC COMMUNICATIONS
Volume 41, Issue 14, Pages 2146-2151Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2010.499487
Keywords
Cage; imine; microporous
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Funding
- North West Development Agency (UK)
- Knowledge Centre for Materials Chemistry
- Royal Society
- EPSRC [EP/H000925/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
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[image omitted] We describe an improved synthesis for a [4+6] imine-linked cage, which was shown recently to exhibit microporosity in the crystalline state and which can be converted by recrystallization to produce either porous or nonporous polymorphs. The original methodology for the synthesis of this molecule resulted in poor yields (approximately 35%). Here, we demonstrate that the cage can be prepared in almost 100% yields and can be isolated with high chemical purity.
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