Journal
SYNTHETIC COMMUNICATIONS
Volume 40, Issue 7, Pages 944-950Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00397910903219542
Keywords
BODIPY; boradiaza-s-indacene; long-wavelength dye
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A difluorosubstituted aza-boron-dipyrromethene derivative with fully chelated boron atom was synthesized by the reaction of BF3 center dot Et2O with 3,3,5,5-tetraarylazadipyrromethene, which was easily prepared from 1,3-diaryl-4-nitro-butan-1-one and ammonium acetate. One fluorine atom of the dye was substituted by pyrrolidine residue. This resulted in a significant bathochromic effect. Ultraviolet absorption and fluorescence emission spectra were recorded, and quantum yields of the obtained compounds were calculated.
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