Journal
SYNTHETIC COMMUNICATIONS
Volume 39, Issue 5, Pages 775-791Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00397910802431149
Keywords
Cyanohydrin; cyanosilylation; L-proline salt; solvent-free condition; TMSCN
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Funding
- Key Laboratory of Organic Synthesis of Jiangsu Province at Suzhou University [S8109108]
- the Natural Science Foundation of Jiangsu Province [BK2006048]
- National Science Foundation of China [20472062, 20672079]
- Nature Science Key Basic Research of Jiangsu Province for Higher Education [06KJA15007, 05KJB150116]
- Jiangsu Provincial Key Laboratory of Fine Petrochemical Technology [KF0402]
- Innovation Project for Graduate Students of Jiangsu Province
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The alkali salt of L-proline was demonstrated to be an efficient and practical catalyst for the cyanosilylation of a wide variety of simple and functionalized carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the corresponding cyanohydrins in good to excellent yields.
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