4.3 Article

Synthesis of hydroxyalkyl-substituted, push-pull chromophores based on diphenylacetylenes and 1,4-bis(phenylethynyl)benzenes

Journal

SYNTHETIC COMMUNICATIONS
Volume 38, Issue 4, Pages 499-516

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397910701796584

Keywords

iodination; 2-methyl-3-butyn-2-ol; palladium; phenylacetylenes; sonogashira

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Six new push-pull chromophores based on phenylacetylenes were prepared: two 1,2-diphenylacetylenes and four 1,4-bis(phenylethynyl)benzenes. The donor amino groups have hydroxyethyl substituents, and the acceptor groups are cyano or nitro. More soluble versions were made by including two methoxy groups on the central phenyl ring.

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