Journal
SYNTHESIS-STUTTGART
Volume 51, Issue 3, Pages 693-703Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610267
Keywords
synthetic methodology; N-acylation; manganese; amide; catalytic reaction
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Funding
- National Natural Science Foundation of China [21402168]
- Scientific Research Foundation of Hunan Provincial Education Department [15B232]
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A practical protocol has been developed here for the Mn(II)-catalyzed N-acylation of amines with high yields using N, N-dimethylformamide and other amides as the carbonyl source. The protocol is simple, does not require any acid, base, ligand, or other additives, and encompasses a broad substrate scope for primary, secondary, and heterocyclic amines.
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