Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 20, Pages 4097-4103Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610534
Keywords
aryletherification; allenes; palladium; stereoselectivity; intermolecular three-component reaction
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A palladium-catalyzed three-component intermolecular aryletherification reaction of ferrocene-substituted allenes, aryl iodides and phenols or alcohols is reported. In this three-component reaction, two new C-C and C-O bonds are formed in one step with high regio- and stereoselectivity. The high selectivity obtained in this reaction can be attributed to the steric effect of the bulky ferrocene group.
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