Journal
SYNTHESIS-STUTTGART
Volume 46, Issue 15, Pages 2007-2023Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378209
Keywords
thiourea; carbonylative armulation; transition metal; cobalt; palladium
Categories
Funding
- National Basic Research Program of China (973 Program) [2010CB833201, 2102CB722602]
- National 863 Program [2013AA092903]
- Natural Science Foundation of China [21372016]
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Thioureas are air and moisture stable, and they can coordinate to various metal centers, making their derivatives versatile ligands for transition-metal-catalyzed reactions. This account provides an overview of recent developments in the use of thioureas as ligands in organometallic-catalyzed reactions, with particular emphasis on their application to the total synthesis of natural products.
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