4.5 Review

Recent Advances in Palladium-Catalyzed C(sp3)-H Activation for the Formation of Carbon-Carbon and Carbon-Heteroatom Bonds

Journal

SYNTHESIS-STUTTGART
Volume 46, Issue 11, Pages 1421-1439

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1338625

Keywords

alkylation; arylation; palladacycles; homogeneous catalysis; organometallic reagents

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Within this review, recent developments in the field of C(sp(3))-H activation catalyzed by palladium are discussed. Both intra- and intermolecular reactions towards carbon-carbon and carbon-heteroatom bonds are covered. In the case of intramolecular reactions, asymmetric versions are reported as well. The main focus of this review is literature of the last five years until late 2013.

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