Journal
SYNTHESIS-STUTTGART
Volume 47, Issue 1, Pages 134-140Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379043
Keywords
palladium; allylic substitution; asymmetric catalysis; indolines; quaternary carbon
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Funding
- Major Basic Research Development Program [G 2010CB833300]
- National Natural Science Foundation of China [21121062, 21032007, 21302205]
- Chinese Academy of Sciences
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
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An efficient and practical method was developed for the synthesis of 2,2-disubstituted indolin-3-ones by palladium-catalyzed asymmetric allylic alkylation. Enantioselective construction of quaternary carbon centers was also realized in this way.
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