Journal
SYNTHESIS-STUTTGART
Volume 45, Issue 5, Pages 615-620Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1318172
Keywords
Co(acac)(2); allylic and benzylic oxidation; tert-butyl hydroperoxide; enones; benzaldehydes; ketones
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Funding
- National Natural Science Foundation of China [20972184]
- national hi-tech research and development program of China [2011AA10A206]
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Various allylic and benzylic substrates were oxidized to the corresponding enones, arenealdehydes and aryl ketones in good yields with tert-butyl hydroperoxide in the presence of catalytic amounts of Co(acac)(2) under mild conditions. The reactivity, selectivity, and scope of the reaction were investigated.
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