Journal
SYNTHESIS-STUTTGART
Volume 46, Issue 2, Pages 189-194Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1338558
Keywords
auranomide; quinazolinobenzodiazepine; intramolecular cyclization; reductive dehydrocyclization; nucleophilic ring opening
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Funding
- GVK Biosciences management
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The first total synthesis of (-)-auranomide C has been achieved. The short synthetic strategy involves a reductive dehydro-cyclization and the nucleophilic ring opening of a fused gamma-lactam. The route allows for ease in synthesizing diverse derivatives in the side chain of the natural product.
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