Journal
SYNTHESIS-STUTTGART
Volume 44, Issue 10, Pages 1526-1534Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290815
Keywords
aldehydes; copper; oxygen; oxygenation; formylation
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Funding
- Nanyang Technological University
- Singapore Ministry of Education
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Copper-catalyzed aerobic methyl/methylene oxygenation of substituted indoles and pyrroles was developed using 1,4-diazabicyclo[2.2.2]octane (DABCO) as an additive in dimethyl sulfoxide (DMSO). Similar aerobic catalytic conditions could also be utilized for direct C-H formylation of C(3) on indoles and C(2) on pyrroles.
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