Journal
SYNTHESIS-STUTTGART
Volume 44, Issue 7, Pages 1030-1036Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1289723
Keywords
aldehyde; zinc; nucleophilic addition; olefination; benzylation
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Funding
- National Natural Science Foundation of China [20962017]
- Natural Science Foundation of Gansu Province, China [1107RJZA263]
- Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education
- Key laboratory Polymer Materials of Gansu Province (Northwest Normal University)
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An efficient and facile copper(II) acetylacetonate catalyzed synthesis of functionalized bis(arylmethyl)zinc reagents from arylmethyl halides and their olefination reaction with aromatic aldehydes is reported. Aluminum trichloride was found to be the key ingredient in these reactions and (E)-stilbenes were obtained in high yields.
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