Journal
SYNTHESIS-STUTTGART
Volume -, Issue 13, Pages 2044-2053Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260607
Keywords
decarboxylative reactions; organocatalytic reactions; malonic acid half thioester; asymmetric catalysis; enantioselectivity
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Funding
- NUS [R-143-000-337-112, R-143-000-376-112]
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This short review summarizes decarboxylative reactions of malonic acid half thio/oxyester mediated by metal complexes and organocatalysts. These biomimetic reactions are inspired by similar reactions catalyzed by polyketide synthase. While they have been known for several decades, this is the first review of these reactions.
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