Journal
SYNTHESIS-STUTTGART
Volume -, Issue 10, Pages 1515-1525Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260006
Keywords
radical reaction; rearrangement; ketones; carboxylic acids; azo compounds
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG)
- FAU Erlangen-Nurnberg
Ask authors/readers for more resources
The reductive ring-opening of hydroperoxides derived from cyclic ketones leads to alkyl radicals which can effectively be trapped by arenediazonium salts. This synthetic transformation yielding azo carboxylic acids or lactams, after a reductive step, can be classified as a radical version of the well-known Beckmann rearrangement. In this article, we present results on the scope, the limitations and possible applications of this new reaction type.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available