Journal
SYNTHESIS-STUTTGART
Volume -, Issue 13, Pages 2245-2253Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1220010
Keywords
arylations; C-H activation; dehydrogenation; ruthenium; triazoles
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Funding
- DFG
- Alexander von Humboldt foundation
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The chemoselectivity of ruthenium-catalyzed C-H bond arylations on triazol-4-yl-substituted arenes was found to depend on the substitution pattern of both substrates. While various aryl chlorides led to products stemming from direct arylations, ortho-substituted aryl halides in combination with ortho-alkylated arenes preferentially resulted in oxidative homo-couplings.
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