Journal
SYNTHESIS-STUTTGART
Volume -, Issue 18, Pages 3037-3062Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1257960
Keywords
copper; cross-coupling; nickel; phosphines; palladium
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Funding
- NRW Graduate School of Chemistry
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This review is a comprehensive account of transition-metal-catalyzed cross-coupling reactions to form C-P bonds. Organized according to the hybridization of the carbon coupling partner, the numerous phosphorus coupling partners are discussed individually. The several putative mechanisms of these transition-metal catalyses are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this chemistry. A separate section is devoted to asymmetric C-P cross-couplings.
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