Journal
SYNTHESIS-STUTTGART
Volume -, Issue 21, Pages 3657-3662Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1258244
Keywords
Prins cyclization; ring-closing metathesis; esterification; reductive ring opening; lactone
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Funding
- CSIR, New Delhi
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A practical stereoselective total synthesis of (3R,5R)-5-hydroxy-de-O-methyllasiodiplodin has been accomplished via Prins cyclization. It exhibits potato microtuber inducing activity. The synthetic sequence involves Prins cyclization, reductive opening of the pyran ring, esterification, and ring-closing metathesis (RCM) as the key steps.
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