Journal
SYNTHESIS-STUTTGART
Volume -, Issue 14, Pages 2454-2466Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1216867
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- Japan Society for the Promotion of Science (JSPS)
- Program for the Promotion of Basic and Applied Research for Innovations in the Bio-oriented Industry (BRAIN)
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The reactions of propargylic oxiranes and aziridines with a platinum catalyst in aqueous media are described. Furans having a variety of substituents were conveniently synthesized by the platinum-catalyzed reaction of propargylic oxiranes. The reaction in the presence of N-iodosuccinimide afforded the 3-iodo-substituted furan, which was further functionalized to tetrasubstituted furans with high efficiency. Propargylic aziridines were also reacted with the platinum catalyst to produce the corresponding substituted pyrroles in good yields.
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