4.5 Article

A New Atom-Economical and Selective Synthesis of Secondary and Tertiary Alkylamines by Means of Cp*Iridium Complex Catalyzed Multiple N-Alkylation of Ammonium Salts with Alcohols without Solvent

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 7, Pages 1220-1223

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1087996

Keywords

ammonium salt; alcohol; amine; N-alkylation; iridium complex

Funding

  1. KAKENHI [19550106]

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A new atom-economical and selective synthetic method for secondary and tertiary alkylamines has been achieved by means of (pentamethylcyclopentadienyl)iridium (Cp*Ir) complex catalyzed multiple N-alkylations of ammonium salts with primary and secondary alcohols without solvent.

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