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Organosilicon Compounds as Water Scavengers in Reactions of Carbonyl Compounds

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 22, Pages 3719-3743

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1217066

Keywords

carbonyl compounds; condensation; organosilicon compounds; water scavengers; chlorotrimethylsilane

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The literature data on the application of organosilicon compounds as water scavengers in reactions of carbonyl compounds is surveyed. The reactions leading to both carbon-carbon (in particular, aldol-type condensations) and carbon-nitrogen bond formation, the synthesis of iminium salts by elimination reactions and heterocyclizations are considered.

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