Reactions of unsaturated azides;: Part 22:: The alkyne azide click chemistry as a synthetic tool for the generation of cage-like triazole compounds

The applicability of the copper(I )-catalyzed click reaction of terminal trialkynes with triazides to the synthesis of cage-like triazole Compounds was determined. A number of starting materials were prepared and several monotriazoles as well as macrocyclic bistriazoles were obtained from the triazide trialkyne reaction. Finally, a tristriazole macrobicyclic compound was synthesized from the previously formed triazole precursors.