4.5 Article

o-benzenedisulfonimide as reusable Bronsted acid catalyst for acid-catalyzed organic reactions

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 9, Pages 1379-1388

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1072564

Keywords

acid catalysis; ether synthesis; ester synthesis; acetal synthesis; pinacol rearrangement

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Acid-catalyzed organic reactions, such as etherification, esterification, acetal synthesis, cleavage, and interconversion, and pinacol rearrangement were carried out in the presence of catalytic amounts of o-benzenedisulfonimide as Bronsted acid catalyst; the conditions were mild and selective. The catalyst was easily recovered and purified, ready to be used in further reactions, with economic and ecological advantages.

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