4.5 Article

H2O2/Tf2O system:: An efficient oxidizing reagent for selective oxidation of sulfanes

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 11, Pages 1682-1684

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1067019

Keywords

sulfoxides; chemoselectivity; environmentally friendly.; triflic anhydride

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A versatile procedure for the oxidation of sulfanes to sulfoxides without any overoxidation to sulfones has been reported. It is noteworthy that the reaction tolerates oxidatively sensitive functional groups and that the sulfur atom is selectively oxidized.

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