Journal
SYNTHESIS-STUTTGART
Volume -, Issue 14, Pages 2191-2198Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1067154
Keywords
indoles; cyclizations; heterocycles; radical reactions; dehydrogenations; microwave irradiation
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A new route providing access to 2-arylindoles has been developed. The synthesis consists of a tin-mediated tandem radical cyclization of appropriate precursors to form 2,3-disubstituted dihydroindoles, which in turn are oxidized to yield the corresponding 2-arylindoles. The reactions proceed smoothly under microwave irradiation, furnishing the desired products in good yields.
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