Journal
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
Volume 43, Issue 2, Pages 203-210Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2012.740714
Keywords
Co(II); Cu(II); imidazole dicarboxylate; supramolecular complex
Funding
- National Natural Science Foundation of China [21071127, 20501017]
- Natural Science Foundation of Henan Educational Committee [2009A150028, 2011A150029]
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Two complexes, [Cu(H2PIDC)2(H2O)] (H3PIDC = 2-propyl- 1H-imidazole-4,5-dicarboxylic acid) (1) and [Co(H2MOPhIDC)2 (H2O)2] (H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid) (2), have been hydro(solvo)thermally synthesized and characterized by IR spectroscopy, elemental analysis, PXRD, and single-crystal X-ray diffraction. Both two complexes show three-dimensional supramolecular structures supported by intermolecular H-bonds. The thermal properties of the two complexes have been investigated as well.
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