Impact of lake breezes on ozone and nitrogen oxides in the Greater Toronto Area

Meteorological and air quality datasets from summertime (May to September, 2010-2012) were analysed in order to assess the influence of lake-breeze circulations on pollutant levels in the Greater Toronto Area (GTA). While previous estimates of the frequency of summer days experiencing lake breezes range between 25 and 32 % for the GTA, a simple algorithm using surface meteorological observations suggested Lake Ontario breezes occurred on 56% of summer days, whereas a more reliable multiplatform approach yielded a frequency of 74%. Data from five air quality stations across the GTA were used to compare air quality on days during which a lake-breeze circulation formed (lake breeze days) versus days when one did not (non-lake breeze days). Average daytime O-3 maxima were 13.6-14.8 ppb higher on lake breeze days relative to non-lake breeze days. Furthermore, the Ontario Ambient Air Quality Criteria (AAQC) for 1-h average O-3 (80 ppb) and 8-h average O-3 (65 ppb) were exceeded only on lake breeze days and occurred on a total of 30 and 54 days throughout the study period, respectively. A causal link between lake-breeze circulations and enhanced O-3 was identified by examining several days in which only some of the air quality sites were inside the lake-breeze circulation. O-3 mixing ratios at sites located within the circulation were at least 30 ppb higher than sites outside the circulation, despite similar temperatures, cloud conditions and synoptic regimes across the region. Rapid O-3 increases were concurrent with the arrival of the lake-breeze front, suggesting O-3-rich air from over the lake is being advected inland throughout the day. Lake-breeze circulations were found to have less impact on nitrogen oxide (NOx) levels. Morning NO was greater on lake breeze days, probably due to the stagnant conditions favourable for lake breeze formation. During the late afternoon, only inland sites experience increased NOx on lake breeze days, likely as a result of being downwind from near-shore city centres. (C) 2015 Elsevier Ltd. All rights reserved.