Journal
SYNLETT
Volume 25, Issue 11, Pages 1626-1628Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378205
Keywords
photochemistry; catalysis; enamines; amides
Categories
Funding
- National Science Foundation of China [20872004, 20972008]
- National 973 Project from the State Ministry of Science and Technology of China
- Shenzhen Bureau of Science, Technology and Information
- Shenzhen Shuang Bai Project
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A series of enamines were photocatalytically cleaved to produce amide products under simple visible-light irradiation from a 45 W household light bulb. Mechanistically, the reactions appear to involve photosensitized formation of a singlet oxygen intermediate and a subsequent [2+2] cycloaddition event.
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