Journal
SYNLETT
Volume 25, Issue 20, Pages 2928-2932Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379366
Keywords
palladium; diarylmethane; arene; benzylation; Hiyama cross-coupling
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Funding
- Chinese National Natural Science Foundation [21173178, 21232005, 21375113]
- National Basic Research Program of China [2012CB821600]
- Program for Changjiang Scholars and Innovative Research Team in University
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An efficient approach to the benzylation of arenes has been developed. The reactions described provide straightforward access to diarylmethanes through Pd-catalyzed coupling of benzylic phosphates with arylsilanes in good to excellent yields. The reaction tolerates a wide range of functionalities such as halide, alkoxyl, and nitro groups.
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