Journal
SYNLETT
Volume 25, Issue 7, Pages 961-964Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1340920
Keywords
aldehyde; aldol reaction; asymmetric catalysis; organocatalysis; proline
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Funding
- Max Planck Society
- HPLC department
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An intriguing effect of electronegative 2,6-substituents on the stereochemical outcome of (S)-proline-catalyzed aldol reactions between benzaldehyde derivatives and acetone is reported. Remarkably high enantioselectivities can be achieved with such substrates.
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