Journal
SYNLETT
Volume 25, Issue 12, Pages 1701-1704Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378278
Keywords
allenes; asymmetric synthesis; cyclization; electrophilic addition; halogenation
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Funding
- WWU Munster
- Fonds der Chemischen Industrie
- DFG [HE 6020/2-1]
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Asymmetric, reagent-controlled bromolactonizations of allenoic acids have been achieved by using (DHQD)(2)PHAL as catalyst. A range of substrates can be cyclized in good yields and moderate to good enantioselectivities under operationally simple conditions.
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