Journal
SYNLETT
Volume 25, Issue 11, Pages 1521-1524Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1341072
Keywords
frustrated Lewis pairs; olefin activation; borane; N-heterocycles
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Funding
- NSERC of Canada
- Canada Research Chair
- NSERC-CGS postgraduate scholarship
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N-Heterocycle-tethered olefins and alkynes are cyclized by addition of the N-heterocycle and B(C6F5)(3) across the unsaturation. This activation is demonstrated to be reversible at high temperatures.
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