4.4 Article

Room-Temperature Arylation of Arenes and Heteroarenes with Diaryliodonium Salts by Photoredox Catalysis

Journal

SYNLETT
Volume 24, Issue 4, Pages 507-513

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1318155

Keywords

arenes; heteroarenes; visible light; aryl radicals; ruthenium

Funding

  1. National Science Foundation [20602024]
  2. Cheung Kong Scholars Program
  3. Program for Changjiang Scholars and Innovative Research Team in University [IRT1070]
  4. Research Funds of Shaanxi Normal University [S2012YB01]

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Aryl radicals produced by irradiation of diaryliodonium salts with visible light under the catalysis of [Ru(bpy)(3)](2+) undergo coupling with a wide range of arenes and heteroarenes, affording various biaryls through direct C-H arylation at room temperature.

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