Journal
SYNLETT
Volume 24, Issue 16, Pages 2032-2044Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1339680
Keywords
alkynes; conjugation; carbon nanomaterials; topochemical polymerization; polydiacetylenes
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Funding
- National Science and Engineering Research Council of Canada (NSERC)
- Fond de Recherche Nature et Technologie du Quebec (FRQ-NT)
- le Centre Quebecois sur les Materiaux Fonctionnels (CQMF)
- Petroleum Research Fund (PRF) through the New Direction Program
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Carbon nanomaterials have been the subject of intense research over the past 20 years. Both the physical and all-organic methods used to prepare them possess advantages and drawbacks regarding purity, batch-to-batch uniformity, large-scale production, and conditions of preparation. In this account, we present an overview of hybrid methods', in which well-defined, reactive organic precursors based on alkynes are self-assembled and transformed using physical stimuli to produce carbon nanomaterials with different sizes, shapes, and functions.
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