Journal
SYNLETT
Volume 24, Issue 4, Pages 437-442Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1318145
Keywords
chiral NHCs; copper; asymmetric hydroboration; aldimines; alpha-amido boronic esters
Categories
Funding
- NSFC [21232009, 21102161]
- SMSTC [11ZR1445800]
- Chinese Academy of Sciences (CAS)
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Non-C-2-symmetric (N-alkyl, N-aryl)-hybrid chiral NHC/Cu(I) complex catalyzed asymmetric hydroboration of N-benzoyl aldimines has been developed. The reaction proceeded smoothly at room temperature, giving alpha-amido boronic esters in excellent yields (up to 94%) and good enantioselectivities (up to 86% ee).
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