Journal
SYNLETT
Volume 24, Issue 12, Pages 1517-1522Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1339173
Keywords
alpha-aminophosphonates; 1,7-azadiynes; alkynes; cyclotrimerization; ruthenium catalysis
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Funding
- RFBR [12-03-00557]
- GDRI [12-03-93111]
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An efficient access to novel trifluoromethyl-substituted phosphonate analogues of 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid (TIC) derivatives based on regioselective ruthenium-catalyzed co-cyclotrimerization of functionalized 1,7-diynes with various alkynes has been developed using RuClCp*cod and preferably Grubbs second-generation catalysts.
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