Journal
SYNLETT
Volume 24, Issue 20, Pages 2763-2767Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1340012
Keywords
cycloadditions; manganese; porphyrins; heterocycles; catalysis; alkenes; ring expansion
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Funding
- JST
- ACT-C
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Grants-in-Aid for Scientific Research [25105729, 21106001, 21106005] Funding Source: KAKEN
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A formal [3+2] cycloaddition between aziridines and alkenes to give the corresponding pyrrolidines was successfully carried out in the presence of a cationic manganese porphyrin catalyst. The use of the porphyrin catalyst allowed, for the first time, styrene derivatives to react with aziridines.
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