Journal
SYNLETT
Volume -, Issue 17, Pages 2491-2496Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1317191
Keywords
copper; oxidation; cyanation; aryl halides; nitriles
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Funding
- National Natural Science Foundation of China [21172060]
- Central Universities (Hunan university)
- China Postdoctoral Science Foundation [2012 M511716]
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A novel, general route for the synthesis of aromatic nitriles is presented that proceeds through Cu(OAc)(2)-catalyzed oxidative cyanation of aryl halides using commercially available nitriles as the cyanide sources and Ag2O/air as the oxidizing agent. It is noteworthy that this work provides a new example of using acetonitrile as the cyanide source for aromatic nitrile synthesis through a Cu-catalyzed oxidative C-C bond cleavage and cyanation process.
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