4.4 Article

Room-Temperature Stille Coupling of Tetraarylstannanes via Palladium-Catalyzed C-H Activation

Journal

SYNLETT
Volume -, Issue 13, Pages 1941-1946

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1316581

Keywords

palladium; room temperature; Stille coupling; tetraarylstannanes; C-H activation

Funding

  1. National Science Foundation [20602024]
  2. Cheung Kong Scholars Program
  3. Program for Changjiang Scholars and Innovative Research Team in University [IRT1070]
  4. Fundamental Research Funds for the Central Universities [GK200902009]

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An effective room-temperature Stille cross-coupling of aryl ureas with tetraarylstannanes via palladium-catalyzed C-H bond activation is reported, providing a mild method for direct arylation of aromatic C-H bonds.

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